<?xml version="1.0" encoding="UTF-8"?><rss version="2.0"
	xmlns:content="http://purl.org/rss/1.0/modules/content/"
	xmlns:dc="http://purl.org/dc/elements/1.1/"
	xmlns:atom="http://www.w3.org/2005/Atom"
	xmlns:sy="http://purl.org/rss/1.0/modules/syndication/"
		>
<channel>
	<title>Comments for Curved Arrow Press Blog</title>
	<atom:link href="http://www.curvedarrowpress.com/wpblog/?feed=comments-rss2" rel="self" type="application/rss+xml" />
	<link>http://www.curvedarrowpress.com/wpblog</link>
	<description></description>
	<lastBuildDate>Thu, 23 Feb 2012 14:41:27 +0000</lastBuildDate>
	<sy:updatePeriod>hourly</sy:updatePeriod>
	<sy:updateFrequency>1</sy:updateFrequency>
	<generator>http://wordpress.org/?v=3.3.1</generator>
	<item>
		<title>Comment on Inductive versus resonance effect? Part 3 by orgopete</title>
		<link>http://www.curvedarrowpress.com/wpblog/?p=128#comment-13</link>
		<dc:creator>orgopete</dc:creator>
		<pubDate>Thu, 23 Feb 2012 14:41:27 +0000</pubDate>
		<guid isPermaLink="false">http://www.curvedarrowpress.com/wpblog/?p=128#comment-13</guid>
		<description>I didn&#039;t think acidity was controversial. I think my opinion(s) about it was. This is based upon two different factors. The three posts about resonance vs inductive effects, the leading comment on the chemicalforums.com forum was a proton is acidic because you can draw a resonance structure of its conjugate base. Then you can read all of my commentary as to why I disagree with this. 

The second reason is due to the notion of electronegativity. An electronegativity theory argues that fluoride should be largely ionic. Acidity is one of the best described measures of ionic content and it clashes with electronegativity. What to do? Dispute acidity? 

I am working on writing a book that I intend to title, &quot;The Nature of the Chemical Bond, Revisited&quot;. In that book I discuss the ionic theory of attraction, Pauling&#039;s proof of it, his theoretical bases for electronegativity theory, his empirical calculation of it, argue weaker than expected bonds disprove the theory, and provide a model which is consistent with a model largely relying upon an inverse square law consistent with the physics of electromagnetic forces. I am working on explaining the different bond strengths that led to electronegativity theory and to explain why some bonds should be stronger than expected and others (the metal hydrides) weaker. Because the laws of physics demand an inverse square relationship, I explain acidity consistent with those forces. I think you should find that electronegativity is false and acidity is not controversial at all. I would hope that you would also learn a whole lot more about chemistry than electronegativity. I have written about bond types, strength, length, reactions, mechanisms, orbitals, atomic theory, Bohr atom, etc.</description>
		<content:encoded><![CDATA[<p>I didn&#8217;t think acidity was controversial. I think my opinion(s) about it was. This is based upon two different factors. The three posts about resonance vs inductive effects, the leading comment on the chemicalforums.com forum was a proton is acidic because you can draw a resonance structure of its conjugate base. Then you can read all of my commentary as to why I disagree with this. </p>
<p>The second reason is due to the notion of electronegativity. An electronegativity theory argues that fluoride should be largely ionic. Acidity is one of the best described measures of ionic content and it clashes with electronegativity. What to do? Dispute acidity? </p>
<p>I am working on writing a book that I intend to title, &#8220;The Nature of the Chemical Bond, Revisited&#8221;. In that book I discuss the ionic theory of attraction, Pauling&#8217;s proof of it, his theoretical bases for electronegativity theory, his empirical calculation of it, argue weaker than expected bonds disprove the theory, and provide a model which is consistent with a model largely relying upon an inverse square law consistent with the physics of electromagnetic forces. I am working on explaining the different bond strengths that led to electronegativity theory and to explain why some bonds should be stronger than expected and others (the metal hydrides) weaker. Because the laws of physics demand an inverse square relationship, I explain acidity consistent with those forces. I think you should find that electronegativity is false and acidity is not controversial at all. I would hope that you would also learn a whole lot more about chemistry than electronegativity. I have written about bond types, strength, length, reactions, mechanisms, orbitals, atomic theory, Bohr atom, etc.</p>
]]></content:encoded>
	</item>
	<item>
		<title>Comment on Inductive versus resonance effect? Part 3 by Altijd</title>
		<link>http://www.curvedarrowpress.com/wpblog/?p=128#comment-12</link>
		<dc:creator>Altijd</dc:creator>
		<pubDate>Thu, 23 Feb 2012 14:13:42 +0000</pubDate>
		<guid isPermaLink="false">http://www.curvedarrowpress.com/wpblog/?p=128#comment-12</guid>
		<description>Why do you think acidity is so controversial? Why does it upset so many people in the chemical world?</description>
		<content:encoded><![CDATA[<p>Why do you think acidity is so controversial? Why does it upset so many people in the chemical world?</p>
]]></content:encoded>
	</item>
	<item>
		<title>Comment on Inductive versus resonance effect? Part 3 by orgopete</title>
		<link>http://www.curvedarrowpress.com/wpblog/?p=128#comment-11</link>
		<dc:creator>orgopete</dc:creator>
		<pubDate>Thu, 23 Feb 2012 06:32:53 +0000</pubDate>
		<guid isPermaLink="false">http://www.curvedarrowpress.com/wpblog/?p=128#comment-11</guid>
		<description>Really? I was responding to the suggestion that ascorbic acid proves acidity is not an inductive function because the &quot;A&quot;-OH was supposed to be more acidic. I argued the beta carbon is the most electron deficient in my post and therefore this example does not prove that the &quot;A&quot;-OH should have been more acidic.</description>
		<content:encoded><![CDATA[<p>Really? I was responding to the suggestion that ascorbic acid proves acidity is not an inductive function because the &#8220;A&#8221;-OH was supposed to be more acidic. I argued the beta carbon is the most electron deficient in my post and therefore this example does not prove that the &#8220;A&#8221;-OH should have been more acidic.</p>
]]></content:encoded>
	</item>
	<item>
		<title>Comment on Inductive versus resonance effect? Part 3 by ALTIJD</title>
		<link>http://www.curvedarrowpress.com/wpblog/?p=128#comment-10</link>
		<dc:creator>ALTIJD</dc:creator>
		<pubDate>Wed, 22 Feb 2012 19:00:58 +0000</pubDate>
		<guid isPermaLink="false">http://www.curvedarrowpress.com/wpblog/?p=128#comment-10</guid>
		<description>As the poster said, you&#039;re not proving anything by qualitatively discussing trends. You need numbers! Paragraphs of writing doesn&#039;t suit atomic science.</description>
		<content:encoded><![CDATA[<p>As the poster said, you&#8217;re not proving anything by qualitatively discussing trends. You need numbers! Paragraphs of writing doesn&#8217;t suit atomic science.</p>
]]></content:encoded>
	</item>
	<item>
		<title>Comment on Inductive versus resonance effect? Part 3 by ALTIJD</title>
		<link>http://www.curvedarrowpress.com/wpblog/?p=128#comment-9</link>
		<dc:creator>ALTIJD</dc:creator>
		<pubDate>Wed, 22 Feb 2012 18:58:00 +0000</pubDate>
		<guid isPermaLink="false">http://www.curvedarrowpress.com/wpblog/?p=128#comment-9</guid>
		<description>Acidity is a property of a system at equilibrium not of individual molecules.</description>
		<content:encoded><![CDATA[<p>Acidity is a property of a system at equilibrium not of individual molecules.</p>
]]></content:encoded>
	</item>
</channel>
</rss>
