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    • Acids and bases 8-13


    Addition

  • bromination 25
  • carbene 78
  • conjugate, 1,4- 54
  • conjugate, 1,4- organometallic 72
  • cyanide 41
  • dihalocarbene 78
  • ethyllithium 38
  • Gilman addition 72
  • Grignard 38, 46, 47
  • HBr 22
  • HBr rearrangement 23
  • HCl 22, 28
  • HCl kinetic and thermodynamic 24
  • hydroboration 27, 30
  • methanol 23
  • Michael 54
  • oxymercuration 26
  • radical of HBr 83
  • water 22, 29
  • Wittig reaction 39

    • Condensation


  • aldol, acid cat. 49
  • aldol, base cat. 49
  • aldol, crossed 50
  • aldol, directed 50
  • Claisen 51
  • Claisen, crossed- 51

    • Curved arrows 2


    Elimination 52

  • Cope 21
  • E1 19
  • E2 18-20
  • Hofmann 21

    Formation

  • Amine 46
  • Acid 46
  • acetylene 20
  • acid 44, 45, 52
  • acid chloride 58
  • aldehyde 40
  • amide 43, 47, 57
  • amine 45
  • bromide 57
  • chloride 56
  • cyanohydrin 41
  • diazonium salt 77
  • enamine 55
  • ester 42, 43, 44
  • Gilman reagent 72
  • Horner-Emmons 39
  • hydrolysis Saponification 45
  • iminium salt 58
  • ketal 40
  • ketone 41, 52
  • nitrile 57
  • oxime 41
  • tosylate 56
  • Wittig reagent 39

    • Hydrolysis

  • amide 44, 45
  • ester 45, 52
  • ketal 40
  • nitrile 47

    • Oxidation

  • Baeyer-Villiger 31
  • chromic acid 65
  • hypochlorite 66
  • osmium tetroxide 69
  • ozone 68
  • PCC 66
  • peracetic acid oxidation 32
  • periodate 69
  • permanganate 69
  • Swern 67
  • Tollens 66

    • Reactions, Other

  • Diels Alder 34-36
  • electrocyclic 37
  • organometallic 70-71

    • Rearrangement

  • Rearrangement, 24, 31, 33
  • addition 23
  • addition HBr 23
  • Baeyer-Villiger 31
  • Curtius 79
  • Hoffmann 80
  • hydroxide 32

    • Reduction

  • aldehyde 59
  • alkyne trans- 64
  • amide 61
  • borohydride 59
  • carboxylic acid 62
  • catalytic 64
  • DIBAL(H) 63
  • ester 60-61, 63
  • imine 62
  • ketone 59-60
  • sodium 64
  • Wolff Kischner 63

    • Resonance structures

    3-6


    Substitution

  • acid catalyzed 16
  • acylation Friedel Craft